File:NDL1138943 大阪工業試験所報告 第18回 第3号 エチレングリコールの合成研究.pdf

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大阪工業試験所報告   (Wikidata search (Cirrus search) Wikidata query (SPARQL)  Create new Wikidata item based on this file)
Author
大阪工業試験所 (商工省)
image of artwork listed in title parameter on this page
Title
大阪工業試験所報告
Volume 第18回 第3号 エチレングリコールの合成研究
Publisher
工業調査協会
Language jpn
Publication date

1942

昭和10-17
Place of publication JP
Source

doi:10.11501/1138943

institution QS:P195,Q477675
Creator
InfoField
商工省大阪工業試験所 編
Publication Place
InfoField
東京
Subject: NDC
InfoField
504
Extent
InfoField
59冊 ; 26-27cm
Material Type
InfoField
Book
Source Identifier: JPNO
InfoField
46035384
Date Digitized: W3CDTF
InfoField
2010-03-31
Audience
InfoField
一般
Title Transcription
InfoField
オオサカ コウギョウ シケンジョ ホウコク
Volume Transcription
InfoField
00270
Publisher Transcription
InfoField
コウギョウ チョウサ キョウカイ
Source Identifier: NDLBibID
InfoField
000000696321
Call Number
InfoField
14.2イ-498イ
Creator: NDLNAId
InfoField
00266723
Type: summaryPartition
InfoField
1
Contents
InfoField
標題

目次

緒言/1

總説/2

1. 合成法の概要/2

2. エチレン及び低級オレフインの根源/5

3. エチレンクロールヒドリン/7

4. エチレングリコール並びに酸化エチレンの生成/9

實驗の部/11

1. エチールアルコールよりエチレンの製造/11

(1) 反應温度の影響/12

(2) アルコール導入の速さ/12

(3) 5糎爐に依る實驗/14

2. エチレンクロールヒドリンの合成/14

3. エチレンクロールヒドリンより直接にエチレングリコールの製造/15

(1) 豫備實驗I./15

(2) エチレングリコールの定量/16

(3) アルカリ濃度の影響/18

(4) 反應温度の影響/19

4. エチレンクロールヒドリンのアルカリ分解 其の一(Statical Study)/20

(1) 豫備實驗II./20

(2) 酸化エチレンの定量/22

(3) アルカリの種類並びに濃度の影響/23

(4) エチレンクロールヒドリンとアルカリの割合/24

(5) 食鹽の影響/25

5. エチレンクロールヒドリンのアルカリ分解 其の二(Kinetic Study)/26

(1) 豫備實驗III./26

(2) エチレングリコールの間接定量法に就て/27

(3) エチレンクロールヒドリンの分解速度並びにエチレングリコールの生成速度の測定/31

6. 酸化エチレンよりエチレングリコールの製造/38

(1) 豫備實驗IV./40

(2) 封管及びオートクレーブの實驗/40

(3) 水量の影響/41

(4) 苛性曹達の觸媒作用に就て/42

實驗結果の考察/46

エチレンクロールヒドリンのアルカリ分解機構に就て/46

(1) エチレンクロールヒドリンに對し苛性曹達同モル若くば少量の場合(1規定溶液の場合)/47

(2) エチレンクロールヒドリンと苛性曹達が同モルにして而も低温稀薄なる場合(1/10規定溶液の場合)/49

(3) エチレンクロールヒドリンに對し苛性曹達過量なる場合/50

報告要旨/50

文献/51

Licensing

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Public domain
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